DETERMINATION OF THERMODYNAMIC AND KINETIC PARAMETERS OF LARGE SCALE CHROMATOGRAPHIC SEPARATION OF SUGAR AND REDUCING SUGAR  

DETERMINATION OF THERMODYNAMIC AND KINETIC PARAMETERS OF LARGE SCALE CHROMATOGRAPHIC SEPARATION OF SUGAR AND REDUCING SUGAR

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作  者:Li Zhong Shu Wenli Liao Yongzhong Huang Peiquan Xu Qingcai 

机构地区:[1]Research Institute of Chemical Engineering, South China UniVersity of Technology, GuangZhou 510641

出  处:《Chinese Journal of Reactive Polymers》1996年第1期84-91,共8页中国反应性高分子(英文版)

摘  要:The parameter identification model of largr scale chromatography separation process is proposed. The Phase equilibrium constants and lumped mass transfer coefficients of sugar and reducing sugar adsorption on D1, D2 and D3 resins as well as the axial dispersion coefficients of the fluid through packed columns are determined by means of the pulse-response experiment technique with an inert substance as a tracer and the chromatography measuring technique. The elution curve calculated from these parameters is good agreement with the experimental elution curve. The sensitivity analysis of these parameters is carried out, and the ressult shows that the elation curves of chromatography separation are more sensitive to the variations Of the Phase equilibrium relationship than to the variation of the axial dispersion as well as the lumped mass transfer coefficients.

关 键 词:Chromatographic Separation RESINS Parameter Determination SUGAR Reducing sugar 

分 类 号:O629.1[理学—有机化学] O652.63[理学—化学]

 

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