Dramatic Solvent Effect in the Reduction of 2,3-Allenoic Acid Esters. A Simple Synthesis of 2,3-Allenols from 2,3-Allenoates  

作　　者：尹少虎 麻生明 焦宁 陶凤岗 

出　　处：《Chinese Journal of Chemistry》2002年第7期707-710,共4页中国化学（英文版）

基　　金：ProjectsupportedbytheMajorStateBasicResearchDevelopmentProgram (No .G2 0 0 0 0 775 0 0 ) ;theNationalNaturalScienceFounda tionofChina ;andShanghaiMunicipalCommitteeofScienceandTechnology .

摘　　要：2,3-Allenols were prepared conveniently from the reduction reaction of 2, 3-allenoates with DIBAL-H (Diisobutylaluminum hydride) in toluene. A dramatic solvent effect was observed for this reaction.2,3-Allenols were prepared conveniently from the reduction reaction of 2, 3-allenoates with DIBAL-H (Diisobutylaluminum hydride) in toluene. A dramatic solvent effect was observed for this reaction.

关 键 词：2 3-allenoates REDUCTION 2 3-allenols 

分 类 号：O623.624[理学—有机化学]