Synthesis and Characterization of β-Cyclodextrin Bonded Metal Porphyrins  

作　　者：李早英 李佳凤 李聪 

机构地区：[1]DepartmentofChemistry,WuhanUniversity,Wuhan,Hubei430072,China

出　　处：《Chinese Journal of Chemistry》2002年第4期399-402,共4页中国化学（英文版）

基　　金：theNationalNaturalScienceFoundationofChina (No .2 9972 0 35 )andtheZiQiangScienceFoundationofWuhanUniversity ,2 0 0 0

摘　　要：Reactions of 5-(p-aminophenyl)-10, 15, 20-triphenyl porphyrin (1) withRu_3(CO)_(12) or M(OCOCH_3)_2 (M= Ni, Mn) afforded metalloporphyrins (4―6), respectively.6-Deoxy-6-io-do-β-cyclodextrin (2) and mono (6-O-trifluoromethanesulfonyl) pennethylatedβ-cyclodextrin (3) reacted with complexes 4―6 to give β-cyclodextrin bonded metal porphyrins(7―9) and permethylated β-cyclodextrin bonded me-tal porphyrins (10―12) respectively. These newcomplexes were identified by MS, IR, UV-visible and ~1H NMR spectra, and elemental analysis.Reactions of 5-(p-aminophenyl)-10, 15, 20-triphenyl porphyrin (1) withRu_3(CO)_(12) or M(OCOCH_3)_2 (M= Ni, Mn) afforded metalloporphyrins (4―6), respectively.6-Deoxy-6-io-do-β-cyclodextrin (2) and mono (6-O-trifluoromethanesulfonyl) pennethylatedβ-cyclodextrin (3) reacted with complexes 4―6 to give β-cyclodextrin bonded metal porphyrins(7―9) and permethylated β-cyclodextrin bonded me-tal porphyrins (10―12) respectively. These newcomplexes were identified by MS, IR, UV-visible and ~1H NMR spectra, and elemental analysis.

关 键 词：β-cyclodextrin bonded metal porphyrins SYNTHESIS CHARACTERIZATION 

分 类 号：O636[理学—高分子化学]