Progress in Pressure Swing Adsorption Models During the Recent 30 Years  

作　　者：曾嵘 关建郁 

出　　处：《Chinese Journal of Chemical Engineering》2002年第2期228-235,共8页中国化学工程学报（英文版）

基　　金：Supported by the National Natural Science Foundation of China (No. 29876011).

摘　　要：The pressure swing adsorption (PSA) models discussed here are divided into three categories: partialdifferential equation model, electrical analogue model and neural network model. The partial differential equationmodel, including equilibrium and kinetic models, has provided an elementary viewpoint for PSA processes. Usingthe simplest equilibrium models, some influential factors, such as pressurization with product, incomplete purge,beds with dead volume and heat effects, are discussed respectively. With several approximate assumptions i.e.,concentration profile in adsorbent, 'frozen' column, symmetry and heat effects of bed wall, the more complexkinetic models can be simplified to a certain degree at the expense of a limited application. It has also been foundthat the electrical analogue model has great flexibility to handle more realistic PSA processes without any additionalhypothesis.The pressure swing adsorption (PSA) models discussed here are divided into three categories: partial differential equation model, electrical analogue model and neural network model. The partial differential equation model, including equilibrium and kinetic models, has provided an elementary viewpoint for PSA processes. Using the simplest equilibrium models, some influential factors, such as pressurization with product, incomplete purge, beds with dead volume and heat effects, are discussed respectively. With several approximate assumptions i.e., concentration profile in adsorbent, 'frozen' column, symmetry and heat effects of bed wall, the more complex kinetic models can be simplified to a certain degree at the expense of a limited application. It has also been found that the electrical analogue model has great flexibility to handle more realistic PSA processes without any additional hypothesis.

关 键 词：gas separation pressure swing adsorption mathematical model 

分 类 号：O647.3[理学—物理化学]