Novel Bipolar Conjugated Polymer Containing Both Triphenylamine and Oxadizole Units  

作　　者：GuangWANG ZeLIU 等 

机构地区：[1]TheStateKeyLaboratoryofPolymerPhysicsandChemistry,ChangzhunInstituteofAppliedChemistry,ChineseAcademyofSciences,Changchun130022 [2]TheStateKeyLaboratoryofPolymerPhysicsandChemistry,ChangzhunInstituteofAp

出　　处：《Chinese Chemical Letters》2002年第5期422-425,共4页中国化学快报（英文版）

基　　金：This work was supported by the National Natural Science Foundation of China (No. 29725410 and 29992530) and Chinese Academy of Sciences (KJ951-A1-501-01).

摘　　要：A novel bipolar conjugated polymer containing triphenylamine and 1, 3, 4-oxadiazole units was synthesized by Suzuki reaction. Its structure and properties were characterized by NMR, IR, UV-Vis, PL spectroscopy and electrochemical measurement. The photoluminescent spectroscopy and cyclic voltammograms measurement demonstrated that the resulting polymer shows blue emission (477 nm) and possesses both electron and hole-transporting property.A novel bipolar conjugated polymer containing triphenylamine and 1, 3, 4-oxadiazole units was synthesized by Suzuki reaction. Its structure and properties were characterized by NMR, IR, UV-Vis, PL spectroscopy and electrochemical measurement. The photoluminescent spectroscopy and cyclic voltammograms measurement demonstrated that the resulting polymer shows blue emission (477 nm) and possesses both electron and hole-transporting property.

关 键 词：Light-emitting polymer bipolar conjugated polymer triphenylamine-containing polymer oxadizole-containing polymer. 

分 类 号：O626.27[理学—有机化学] O625[理学—化学]