Efficient Debromination of Vicinal a, b-Dibromo Carboxylic Acid Derivatives with the Sm/HOAc System  

Efficient Debromination of Vicinal α,β—Dibromo Carboxylic Acid Derivatives with the Sm/HOAc System

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作  者:XiaoXiaWANG YongMinZHANG 

机构地区:[1]DepartmentofChemistry,ZhejiangUniversity(XixiCampus),Hangzhou310028 [2]StateKeyLaboratoryofOrganometallicChemistry,ShanghaiInstituteofOrganicChemistry,ChineseAcademyofSciences,Shangha

出  处:《Chinese Chemical Letters》2002年第6期499-500,共2页中国化学快报(英文版)

基  金:Project supported by the National Natural Science Foundation of China(No.29872010);the Natural Science Foundation of Zhejiang Province(No.298067)

摘  要:The ? ?vicinal dibromo carboxylic acid and its derivatives were debrominated with Sm/HOAc system to afford the corresponding cinnamic acid and its derivatives in good yields under mild conditions.

关 键 词:DEBROMINATION vicinal dibromides a b-unsaturated carboxylic acid derivatives Samarium. 

分 类 号:O625.22[理学—有机化学] O621[理学—化学]

 

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