Insertion of Selenium into Zinc Carbon Bond and Application in Synthesis of Arylselenoester  

作　　者：XinHuaXU WenQiLiU 

机构地区：[1]CollegeofChemistryandChemicalEngineering,HunanUniversity,Changsha410082 [2]DepartmentofChemistryofChenzhouTeachercollege,Chenzhou423000

出　　处：《Chinese Chemical Letters》2002年第4期283-284,共2页中国化学快报（英文版）

摘　　要：Selenium was inserted into the zinc carbon bond of aryl zinc halides to form corresponding zinc selenoates. They reacted in THF-HMPA with acylhalides to afford the selenoesters in high yields.Selenium was inserted into the zinc carbon bond of aryl zinc halides to form corresponding zinc selenoates. They reacted in THF-HMPA with acylhalides to afford the selenoesters in high yields.

关 键 词：SELENIUM insertion reaction zinc carbon bond acylhalides selenoester. 

分 类 号：O627.61[理学—有机化学] O614[理学—化学]