三维无机-有机杂化骨架微孔材料──[Co_3(BTC)(HBTC)(H_2BTC)(C_2H_4O_2)_3]·3(DMF)·6(H_3O)的合成与结构  

A 3-D Inorganic-organic Hybrid Framework Microporous Material──Synthesis and Characteristic of [Co_3(BTC)(HBTC)(H_2BTC)(C_2H_4O_2)_3]·3(DMF)·6(H_3O)

作　　者：方千荣[1] 石鑫[1] 辛明红[1] 吴刚[1] 田歌[1] 朱广山[1] 李亚丰[1] 叶玲[1] 王春雷[1] 张震东[1] 唐璐璐[1] 裘式纶[1] 

机构地区：[1]吉林大学化学学院,无机合成与制备化学国家重点实验室,长春130023

出　　处：《高等学校化学学报》2003年第1期28-30,共3页Chemical Journal of Chinese Universities

基　　金：国家重大基础研究计划"973"项目 (批准号 :G2 0 0 0 0 775 0 7);国家自然科学基金 (批准号 :2 9873017;2 0 10 10 0 4)资助

摘　　要：Compound [Co 3(BTC)(HBTC)(H 2BTC)(C 2H 4O 2) 3]·3(DMF)·6(H 3O) was synthesized under mild conditions and its crystal structure was determined by using single crystal X-ray diffraction. The crystal structure was solved by direct method and refined by full-matrix least-square method. The crystal is monoclinic and belongs to space group Cc with a=2.645 3(5) nm, b= 1.670 4(3) nm, c=1\^821 6(4) nm, β=128.16(3) °, V=6.329(2) nm 3, Z=2 , D c=20.200 Mg/m 3, M r= 1 314.744, μ=10.274 mm -1, F(000) =38 226, GOF=0.99, R=0.094 1, ωR=0.257 3.Compound [Co 3(BTC)(HBTC)(H 2BTC)(C 2H 4O 2) 3]·3(DMF)·6(H 3O) was synthesized under mild conditions and its crystal structure was determined by using single crystal X-ray diffraction. The crystal structure was solved by direct method and refined by full-matrix least-square method. The crystal is monoclinic and belongs to space group Cc with a=2.645 3(5) nm, b= 1.670 4(3) nm, c=1\^821 6(4) nm, β=128.16(3) °, V=6.329(2) nm 3, Z=2 , D c=20.200 Mg/m 3, M r= 1 314.744, μ=10.274 mm -1, F(000) =38 226, GOF=0.99, R=0.094 1, ωR=0.257 3.

关 键 词：三维无机-有机杂化骨架微孔材料 合成 沸石 分子筛 晶体结构 微孔材料 [Co3(BTC)(HBTC)(H2BTC)(C2H4O2)3]·3(DMF) ·6(H3O) 

分 类 号：TQ424.25[化学工程]