丙烯醇在质子交换膜燃料电池反应器中的电化学加氢  

Electrochemical Hydrogenation of Allyl Alcohol Applying PEM Fuel Cell Reatctor

作　　者：袁晓姿[1] 和庆钢[1] 林琳[1] 马紫峰[1] 

机构地区：[1]上海交通大学化工系,上海200240

出　　处：《化学反应工程与工艺》2002年第4期328-333,共6页Chemical Reaction Engineering and Technology

基　　金：国家自然科学基金资助项目 (2 0 0 76 0 2 6 )

摘　　要：利用质子交换膜燃料电池 (PEMFC)原理 ,设计了 PEMFC加氢反应系统装置 ,研究了 PEMFC加氢反应器中丙烯醇的电化学加氢。实验表明 ,丙烯醇能够在阴极转化为正丙醇 ,同时产生电能。并讨论了各种因素 (温度、浓度、反应物流量、催化剂载量等 )对丙烯醇加氢反应的影响。A device for the electro-hydrogenation was designed by using PEM fuel cell. The hydrogenation of allyl alcohol (AA) was studied with the PEM fuel cell system. It was found that AA can be converted to 1-propanol selectively at the cathode and no side reactions were observed. In the meantime, D.C. power was generated continuously. Factors and considerations involved in the reduction of AA and power production were also discussed.

关 键 词：丙烯醇 电化学加氢 质子交换膜燃料电池 反应器 

分 类 号：TM911.4[电气工程—电力电子与电力传动]