由Mg-Fe(Ⅱ)-Fe(Ⅲ) LDH层状前体制备MgFe_2O_4尖晶石的研究  

Investigation of MgFe_2O_4 Spinels Prepared from Layered Magnesium-Iron(Ⅱ)-Iron(Ⅲ) Hydrotalcite Precursors

作　　者：刘俊杰[1] 李峰[1] EVANS D.G 段雪[1] 

机构地区：[1]北京化工大学可控化学反应科学与技术基础教育部重点实验室,北京100029

出　　处：《化学学报》2003年第1期51-57,共7页Acta Chimica Sinica

基　　金：国家自然科学基金(No.2 0 0 760 0 3)资助项目

摘　　要：提出了一种由层状前体合成单一晶相镁铁尖晶石的新方法,首先对Mg Fe(Ⅱ) Fe(Ⅲ)水滑石的制备进行了系统研究,成功合成了Mg2 +/Fe2 +/Fe3+摩尔比分别为 1/2/1,4/5/3,2/1/1的系列水滑石层状前体,结果表明在以上三种投料比下均可制备出晶型较好的水滑石层状前体,并探讨了合成条件对晶体结构的影响规律.在此基础上,利用X射线衍射、振动样品磁强计和穆斯堡尔谱等手段研究了层状前体焙烧产物的结构、组成、磁性及微观信息,研究表明当Mg2 +/Fe2 +/Fe3+投料摩尔比为 2/1/1时。The purpose of this work is to synthesize a single phase spinel from a layered magnesium-iron(Ⅱ)-iron(Ⅲ) hydrotalcite precursors. This paper reports a systematic investigation of the preparation of Mg-Fe(Ⅱ)-Fe(Ⅲ) hydrotalcites, and several hydrotalcites with different Mg 2+/Fe 2+/Fe 3+ molar ratios in the layers were obtained. When the Mg 2+/Fe 2+/Fe 3+ molar ratio in the stock solution is equal to 1/2/1, 4/5/3 or 2/1/1, a well crystallized hydrotalcites were obtained. The effects of various reaction conditions on the crystal structure were also investigated. The hydrotalcites were characterized by XRD, VSM and Mssbauer spectroscopy. When the Mg 2+/Fe 2+/Fe 3+ molar ratio in the reaction mixture was 2/1/1, the material obtained by calcining the resulting hydrotalcite was a single phase spinel.

关 键 词：MgFe2O4尖晶石 镁铁铁水滑石 共沉淀 磁性 铁氧体 软磁材料 

分 类 号：TM27[一般工业技术—材料科学与工程]