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作 者:肖景林[1]
出 处:《发光学报》1992年第1期26-35,共10页Chinese Journal of Luminescence
基 金:内蒙自然科学基金
摘 要:本文研究多原子极性晶体中表面激子的性质.采用线性组合算符和拉格朗日乘子法,导出强耦合多原子极性晶体中表面激子的有效哈密顿量,得到了强耦合表面激子的重正化质量.Since Haken had firstly studied the exciton in polar crystals, a lot of scholars discussed the exciton but many of them mainly concentrated their attention on the weak and intermediate coupling cases. In the early 1970's, Huybrechts proposed a linear combination operator method, by which a strong-coupling polaron was studied.S.W.Gu et al discussed the internal motion of strong-coupling exciton in polar 'crystal by using the method advanced by Huybrechts. The properties of the exciton in the surface layer of crystals influenca the optical properties of the crystals very remarkably.Most polar crystals are diatomic.In these crystals there is only one mode of longitudinal optical (LO) phonon. The properties of crystals have been studied by a great variety of techniques, in which discussions are limited only for the case of one LO phonon branch. However, a large number of polar crystals, with several atoms per unit cell, have more than one LO phonon branch. For example, in cuprite such as CuO2 there are two LO phonon modes and TiO2, GaAsi-,Pt,and, in a large number of perovskites (SrTiO3, LiNbO3....) and quaternary compound semiconductor crystal (AlGaAsSb....) there are more than two modes. In recent years, a lot of scholars investigated the polaron problem of multiple LO phonon branches. However, the exciton in polyatomic polar crystal has not yet been investigated. The ground state energy of the polaron in polyatomic polar crystal is now calculated by using Haga method and the effective Hamiltonian of the exciton in polyatomic polar crystal by means of perturbation method.In this paper, studies on some properties of a strong-coupling surface exciton in polyatomic polar crystals are reported. An effective Hamiltonian of the surfaca exciton is derived by using a linear-combination-operator and Lagrange multiplier method, The renormalized mass of a strong-coupling surface exciton is obtained.In the case of multiple LO phonon branches, the total Hamiltonian of a polyatomic crystal can be written byWe introduce the creat
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