酰基吡唑酮缩氨基硫脲Cu(Ⅱ)、Ag(Ⅰ)配合物的合成及表征  

Synthesis and Characterization of Cu(Ⅱ) and Ag(Ⅰ) Complexes of Furoylpyrazolone-thiosemicarbazone

作　　者：杨昱[1] 李锦州[1] 沙靖全[1] 于文锦[1] 

机构地区：[1]哈尔滨师范大学化学系,黑龙江哈尔滨150080

出　　处：《化学与粘合》2003年第1期18-19,36,共3页Chemistry and Adhesion

基　　金：黑龙江省自然科学基金资助项目 0 1 -B0 6 ;教育部重点科技基金资助项目 0 2 0 53

摘　　要：合成了含硫席夫碱试剂1-苯基-3-甲基-4-(α-呋喃甲酰基)吡唑啉酮-5缩氨基硫脲(L)及其铜,银的配合物。元素分析及摩尔电导值表明新配合物的组成为[CuL2]·4H2O,[AgL]NO3·C2H5OH。通过红外光谱、紫外光谱、差热-热重对配合物进行表征。A new Shiff base containing sulphur,1-phenyl-3methyl-4-(α-furoyl) pyrazolone-5 -thiosemicarbazone(L) and its copper and silver complexes was synthesized. Elemental analysis and the value of molecular conductance showed that the general formula of the complexes were ·4H2O and NO3·C2H5OH. They were characterized with IR, UV-visible and TG-DTA.

关 键 词：酰基吡唑酮缩氨基硫脲 Cu(Ⅱ) Ag(Ⅰ) 配合物 表征 铜(Ⅱ) 银(Ⅰ) 

分 类 号：O614.121[理学—无机化学] O614.122[理学—化学]