含3-甲基苯基-2,3-二氮杂萘-1-酮结构聚醚酰胺的合成、表征与性能  

Synthesis, Characterization and Property of Poly(aryl ether amides) from 2-(4-Aminophenyl)-4-(3-methyl-4-aminophenoxy)-2,3-phthalazinone

作　　者：朱秀玲[1] 蹇锡高[1] 卢冶[1] 王瑞玲[1] 张元红[1] 

机构地区：[1]大连理工大学高分子材料系,大连116012

出　　处：《高等学校化学学报》2003年第2期355-358,共4页Chemical Journal of Chinese Universities

基　　金：国家自然科学基金 (批准号 :5 94730 19)资助

摘　　要：合成了一种新型芳香二胺双 -( 4 -氨基苯基 ) -4 -( 3-甲基 -4 -苯氧基 ) -2 ,3-二氮杂萘 -1 -酮 ( 1 ) [2 -( 4 -aminophenyl) -4 -( 3-methyl-4 -phenoxy) -2 ,3-phthalazinone-1 ,DAMPP].采用 Yamazaki体系 ,二胺 ( 1 )能与多种芳香二酸进行溶液亲核缩聚反应 ,制得一类新型聚芳醚酰胺 ,其特性粘度为 0 .4 0～ 0 .6 0 d L/g;以 MS,FTIR和 1 H NMR等分析手段研究了新型二胺单体及其聚合物的结构 ;利用 DSC和 TGA研究了聚合物的耐热性能 ,结果表明 ,新型聚芳酰胺具有高的玻璃化转变温度为 5 98～ 6 2 0 K,N2 气气氛中 1 0 %热质量损失温度在 6 73K以上 .聚合物 2 a～ 2 c的表面电阻系数为 3.75× 1 0 1 4 ～ 9.87× 1 0 1 5Ω,体积电阻系数为1 .39× 1 0 1 6～ 4 .0 9× 1 0 1 6Ω·cm.聚合物在二甲基甲酰胺、 1 -甲基吡咯烷酮和间甲酚等极性有机溶剂中可溶解 ,并经浇注得到透明、韧性薄膜 .A novel aromatic diamine 2-(4-aminophenyl)-4-(3-methyl-4-aminophenoxy)-2,3-phthalazinone-1(1, DAMPP) containing aza heterocycle was synthesized in a higher yield starting from 4-(3-methyl-4-hydroxyphenyl)-2,3-phthalazinone-1(OM-HPPZ) via two steps conveniently. Diamine 1 polymerized with three aryl dicarboxylic acids to prepare a series of new aromatic polyamides in a high yield using Yamazaki phosphorylation method. The synthesized polymer has a high molecular weight with the inherent viscosity in the range of 0.40-0.60 dL/g. They exhibited high glass transition temperatures of 598-620 K and good thermostable properties with the 10% weight loss temperature above 673 K(in nitrogen). The range of their surface resistance coefficients is 5.89×10 15- 9.87×10 15 Ω and the range of volume resistance coefficients is 1.39×10 16-4.09×10 16 Ω·cm. These polymers were readily soluble in polar solvents such as NMP, DMF and m-cresol etc, clear tough films were cast from their DMAc solutions. The structures of diamine 1 and polymers obtained was confirmed by MS, FTIR and 1H NMR, which are consistent with the designed structure.

关 键 词：3-甲基苯基-2 3-二氮杂萘-1-酮 聚醚酰胺 合成 表征 性能 聚芳酰胺 杂环聚合物 溶解性 工程塑料 

分 类 号：TQ323.7[化学工程—合成树脂塑料工业] O633.5[理学—高分子化学]