过渡元素钼钨钒磷五元杂多配合物的合成、表征以及与奎宁的取代反应  

Synthesis,Characterization of Pentatomic Transition Elements Molybdotugstovanadophosphoric Heteropoly Complexes,the Replaced Reaction with Quinine

作　　者：周百斌[1,2] 韦永德[3] 王玉和[1] 马慧媛[1] 李中华[3] 郭元茹[3] 周宏立[1] 

机构地区：[1]哈尔滨师范大学化学系 [2]哈尔滨工业大学应用化学系,哈尔滨150001 [3]哈尔滨工业大学应用化学系

出　　处：《无机化学学报》2003年第3期291-294,共4页Chinese Journal of Inorganic Chemistry

基　　金：国家自然科学基金资助项目(No.29671009);黑龙江省教育厅科研项目资助(No.10511035)。

摘　　要：Eight new complexes were synthesize d for the first time.The compounds which have the general formula K x H 2 [PM(OH 2 )Mo 7 W 2 V 2 O 39 ]·nH 2 O(M=Cr 3+ ,Mn 2+ ,Fe 3+ ,Co 3+ ,Ni 2+ ,Cu 2+ ,Zn 2+ ,Cd 2+ ;x=4or 5)were de-termined by conductance titration a nd elemental analysis.The analysis of IR,UV,XRD and ESR show that the products hold the Keggin structure a nd TG-DTA,IR,XRD at various tempera tures and water solubility test also give the evidences that the range of pyrolysis temperature is 300～350℃.T he study on the substitutional reaction of coordinated water by optical ligand quinine shows that the S N 2nucleophilic substitution occure s when Ni is con-tained in the compound and S N 1nucleophilic substitution occure s when Cu is contained.These also con firmed that the transitional metals are in the in ner sphere of the complexes.Eight new complexes were synthesize d for the first time.The compounds which have the general formula K x H 2 [PM(OH 2 )Mo 7 W 2 V 2 O 39 ]·nH 2 O(M=Cr 3+ ,Mn 2+ ,Fe 3+ ,Co 3+ ,Ni 2+ ,Cu 2+ ,Zn 2+ ,Cd 2+ ;x=4or 5)were de-termined by conductance titration a nd elemental analysis.The analysis of IR,UV,XRD and ESR show that the products hold the Keggin structure a nd TG-DTA,IR,XRD at various tempera tures and water solubility test also give the evidences that the range of pyrolysis temperature is 300～350℃.T he study on the substitutional reaction of coordinated water by optical ligand quinine shows that the S N 2nucleophilic substitution occure s when Ni is con-tained in the compound and S N 1nucleophilic substitution occure s when Cu is contained.These also con firmed that the transitional metals are in the in ner sphere of the complexes.

关 键 词：过渡元素 钼钨钒磷杂多阴离子 相转移 奎宁 

分 类 号：O614.4[理学—无机化学]