1,4,8,11,15,18,22,25-八丁氧基酞菁镍(Ⅱ)的合成与性质  

Synthesis and study on properties of 1,4,8,11,15,18,22,25-octabutoxy phthalocyanine nickel(Ⅱ)

作　　者：李邦玉[1] 方昕[1] 杨素苓[1] 王俊东[1] 陈耐生[1] 黄金陵[1] 

机构地区：[1]福州大学化学系功能材料研究所

出　　处：《化学研究与应用》2003年第1期75-77,57,共4页Chemical Research and Application

基　　金：国家自然科学基金资助项目(29871008)

摘　　要：1,4,8,11,15,18,22,25-octabutoxy phthalocyanine nickel(Ⅱ) was synthesized by refluxing 3,6-dibutoxy phthalonitrite with anhydrous nickel chloride in n-amyl alcohol solvent in the presence of 1,8-diazabicycloundec-7-ene(DBU).The product was characterized by elemental analysis.IR,UV-Vis and fluorescence emission spectra.The thermal stability was studied by TG and TDG.The redox potentials was measured using cyclic voltammetry(CV).1,4,8,11,15,18,22,25-octabutoxy phthalocyanine nickel(Ⅱ) was synthesized by refluxing 3,6-dibutoxy phthalonitrite with anhydrous nickel chloride in n-amyl alcohol solvent in the presence of 1,8-diazabicycloundec-7-ene(DBU).The product was characterized by elemental analysis.IR,UV-Vis and fluorescence emission spectra.The thermal stability was studied by TG and TDG.The redox potentials was measured using cyclic voltammetry(CV).

关 键 词：丁氧基 酞菁镍(Ⅱ) 合成 结构表征 

分 类 号：O614.813[理学—无机化学]