2-氯苯甲醛单缩二氨基硫脲配合物的电化学合成  

The direct electrochemical synthesis of Ti(Ⅳ)、Ni(Ⅱ)、Cu(Ⅰ)complexes of mono(2-chlorobenzaldehyde)thiosemicarbazone

作　　者：刘建宁[1] 仵博万[1] 张兵[1] 于新桥[1] 赵建设[2] 

机构地区：[1]庆阳师范高等专科学校化学系,甘肃西峰745000 [2]西北大学化学系,陕西西安710069

出　　处：《化学研究与应用》2003年第1期85-87,共3页Chemical Research and Application

摘　　要：Ti(Ⅳ),Ni(Ⅱ),Cu(Ⅰ) complexes bearing mono(2-chlorobenzaldehyde)-thiosemicarbazone(HL) were synthesized in non-aqueous solvent containing ligand(HL) by the electrochemical oxidation of anodic metal with Ti,Ni and Cu,respectively.The complexes were characterized by elemental analysis,IR,UV,magnetic susceptibility and molar conductivity etc.Ti(Ⅳ),Ni(Ⅱ),Cu(Ⅰ) complexes bearing mono(2-chlorobenzaldehyde)-thiosemicarbazone(HL) were synthesized in non-aqueous solvent containing ligand(HL) by the electrochemical oxidation of anodic metal with Ti,Ni and Cu,respectively.The complexes were characterized by elemental analysis,IR,UV,magnetic susceptibility and molar conductivity etc.

关 键 词：2-氯苯甲醛单缩二氨基硫脲 配合物 电化学合成 

分 类 号：O614.4[理学—无机化学]