手性奎宁-卟啉锰催化剂的合成及其催化性能  

Synthesis and catalytic properties of chiral quinine-porphyrin Mn(Ⅲ)complexes

作　　者：王亚军[1] 刘彦钦[2] 韩士田[2] 

机构地区：[1]湖州师范学院化学系,浙江湖州313000 [2]河北师范大学化学系,河北石家庄050091

出　　处：《化学研究与应用》2003年第1期95-96,共2页Chemical Research and Application

基　　金：河北省自然科学基金资助项目(299194)

摘　　要：Six quinine-porphyrin Mn? complexes was synthesized by a certain of new chiral quinine-porphyrin.Their catalytic properties for the epoxidation of olefins in two-phase system (CH 2Cl 2/H 2O) were studies.The result indicated these not only can enhance catalyzing activity,but also showed obvious phase-transfer function.That the reaction condition had affacfed the results of epoxidation.Six quinine-porphyrin Mn? complexes was synthesized by a certain of new chiral quinine-porphyrin.Their catalytic properties for the epoxidation of olefins in two-phase system (CH 2Cl 2/H 2O) were studies.The result indicated these not only can enhance catalyzing activity,but also showed obvious phase-transfer function.That the reaction condition had affacfed the results of epoxidation.

关 键 词：奎宁-卟啉锰 催化剂 烯径环氧化 相转移催化 

分 类 号：O627.8[理学—有机化学]