四水五硼酸铯及其饱和溶液的振动光谱分析  

Vibrational spectroscopic analysis of CsB_5O_8·4H_2O and its saturated aqueous solution

作　　者：刘志宏[1] 

机构地区：[1]陕西师范大学化学与材料科学学院,陕西西安710062

出　　处：《化学研究与应用》2003年第1期106-108,共3页Chemical Research and Application

摘　　要：The differential FTIR spectroscopy and Raman spectra of CsB5O8·4H2O and its saturated aqueous solution were studied.The assignments of the recorded FTIR frequencies and Raman shift were given.The main polyborate anions and their interaction in borate aqueous solution were proposed.The relationship between the existing forms of polyborate anions and the crystallizing solid phase,CsB5O8·4H2O,was obtained.The differential FTIR spectroscopy and Raman spectra of CsB5O8·4H2O and its saturated aqueous solution were studied.The assignments of the recorded FTIR frequencies and Raman shift were given.The main polyborate anions and their interaction in borate aqueous solution were proposed.The relationship between the existing forms of polyborate anions and the crystallizing solid phase,CsB5O8·4H2O,was obtained.

关 键 词：振动光谱 四水五硼酸铯 硼氧配阴离子 

分 类 号：O561.3[理学—原子与分子物理]