N-二茂铁甲酰基-芳基羟胺及其铜(Ⅱ)螯合物的合成与表征  

Synthesis and Characterization of Some N-Ferrocenoyl- arylhydroxylamines and Their Cu( Ⅱ) Chelates

作　　者：张文[1] 边占喜[1] 李逢泽[1] 

机构地区：[1]内蒙古大学化学系,呼和浩特010021

出　　处：《高等学校化学学报》1992年第4期478-480,共3页Chemical Journal of Chinese Universities

摘　　要：二茂铁甲酰羟胺衍生物分子中含有N-羟基和α-羰基,可与过渡金属形成螯合物.我们试图将该类螯合物用作复合固体推进剂的燃速调节剂,为此,研究了该类化合物的合成方法及其性质,并使它们与铜(Ⅱ)螯合制成铜螯合物.本文报道7种N-二茂铁甲酰基-芳基羟胺和7种铜螯合物,均未见文献报道.反应式如下:A series of N-ferrocenoylarylhydroxylamines have been synthesized by the partial acy-lation of arylhydroxylamines with the ferrocenoyl chloride. These organometallic compounds can act as ligands for metal chelation and their Cu( Ⅱ ) chelates have been isolated. The ligands and chelates have been characterized by elemental analysis, IR and 1H NMR spectra. The chelates can act as solid propellant burning rate modifiers.

关 键 词：二茂铁甲酰化 芳基羟胺 铜螯合物 

分 类 号：O614.121[理学—无机化学]