系列类立方烷型Fe_4S_4簇合物的XPS分析  

XPS Analysis of Cabane-like Fe_4S_4 Clusters

作　　者：魏诠 徐吉庆[1] 南玉明[1] 千吉松 蔡辉[1] 闫英卓 

机构地区：[1]吉林大学化学系,长春130023

出　　处：《高等学校化学学报》1992年第5期636-638,共3页Chemical Journal of Chinese Universities

摘　　要：对7种类立方烷型Fe_4S_4簇合物进行了XPS分析,得到了中心离子Fe的价态,给出了系列Fe_4S_4中骨架硫的结合能,由峰合成结果给出各种S、N的比例与按结构式计算的结果相同。The XPS of cabane-like Fe4S4 clusters were studied. The valence of Fe was examined, the 2p binding energy of the framework S in Fe4S4 is first reported. The proportion of all sorts of S and N by peak synthesis is in agreement with the values obtained from the calculation on the basis of structure formulas.

关 键 词：类立方烷结构 铁硫簇合物 

分 类 号：O614.811[理学—无机化学]