二邻巯基苯酚-苯甲酰肼合钼(Ⅳ)酸双三乙基亚铵三元固态配合物的合成及谱学特性  

Syntheses and Spectroscopic Properties of Ternary Complex(Et_3NH)_2[(SC_6H_4O)2MO]

作　　者：翟应离[1] 王修建[1] 王秋莹[1] 

机构地区：[1]兰州大学化学系,兰州730000

出　　处：《高等学校化学学报》1992年第10期1197-1200,共4页Chemical Journal of Chinese Universities

摘　　要：以(Bu_4N)_4Mo_8O_(26)为原料,以邻巯基苯酚和苯甲酰肼为配体,在甲醇中合成了未见报道的单核三元配合物二邻巯基苯酚-苯甲酰肼合钼(Ⅳ)酸双三乙基亚铵.通过元素分析、红外光谱、~1H NMR谱、电子光谱、差热-热重分析对化合物的性质进行了表征,发现它是无端基氧钼配合物,并提出了其可能结构.The ternary complex of monomolybdenum (Et3NH)2[(SC6H4O)2Mowas synthesized in methanol with o-mercaptophenol and benzoylhydrazine as the ligand and (Bu4N[MG9O26]as the parent The properties of the complex were characterized by elemental analysis,molar conductivity,electronic spectra,infrared spectra,1H NMR spectra and TG-DTA,The most possible structure is proposed on the basis of the spectral data and the IR spectra show that the complex has not terminal oxygen atoms,

关 键 词：钼硫键 钼氮键 合成 钼络合物 

分 类 号：O614.612[理学—无机化学]