热动力学的研究(XXlV)——等浓度三级反应的热动力学  

Studies on Thermokinetics (XXIV)——Thermokinetics Method for the Third Order Reaction

作　　者：王瑞林[1] 段治华[1] 曾宪诚[1] 秦自明[1] 邓郁[1] 

机构地区：[1]四川大学化学系,成都610064

出　　处：《高等学校化学学报》1992年第11期1440-1443,共4页Chemical Journal of Chinese Universities

基　　金：国家自然科学基金

摘　　要：本文根据热动力学的基础理论,建立了等浓度三级反应的无量纲参数法,并用此法研究了甲醛与氨反应的热动力学.实验测得的速率常数与文献值吻合.On the theoretical basis of thermokinetics proposed in the literature,the method of di-mensionless parameters for the third order reactions are derived in this paper.This method has been used to study the formation of hexamethylenetetramine in aqueous solutions at two different temperatures.The rate constants of these reactions calculated by using this method are in agreement with the values in literature.And therefore,the foundamental equations of thermokinetic method for the third order reactions are believed to be correct.

关 键 词：热动力学 等浓度 三级反应 

分 类 号：O643[理学—物理化学]