Synthesis and Crystal Structure of a Three-dimensional Manganese(Ⅱ)Complex Constructed via Covalent and Hydrogen Bonds  

作　　者：WANGRui－Hu ChenLi－Hua 等 

机构地区：[1]StateKeyLaboratoryofStructuralChemistry,FujianInstituteofResearchontheStructureofMatte,TheCineseAcademyofSciences,Fuzhou,Fujian350002,China [2]JianouInstituteofEnvironmentsupervisi

出　　处：《Chinese Journal of Structural Chemistry》2003年第1期50-54,共5页结构化学（英文）

基　　金：supported by the National Natural Science Foundation of China (No. 29890210) and the Key Project of the Chinese Academy of Sciences (KJCX2-H3)

摘　　要：The assembly of 1,4-benzenedicarboxylic acid (H2bdc), 4,4?bipyridine (4,4?bipy), trimethyltin chloride and MnBr24H2O in hydrothermal conditions gave rise to a hydrogen-bonded three-dimensional complex {[Mn(4,4?bipy)4H2O](bdc)}n which has been characterized by single- crystal X-ray diffraction. The complex crystallizes in the monoclinic system, space group P2/n with a = 7.0001(2), b = 11.5540(3), c = 11.4192(1) ? = 101.754(2)? V = 904.21(4) 3, Z = 2, C18H20MnN2O8, Mr = 447.30, Dc = 1.643 g/cm3, F(000) = 462 and m(MoK? = 0.783 mm-1. The final R and wR are 0.0499 and 0.1301, respectively for 1335 observed reflections with I ≥ 2(I). The Mn (Ⅱ) is six-coordinated in a distorted octahedral geometry. 4,4?Bipyridine in a m-bridge mode links [Mn(H2O)4]2+ into a linear cation chain. bdc acts as a counter anion and links the linear chains into a three-dimensional structure through hydrogen bonds.

关 键 词：manganese (Ⅱ) complex crystal structure synthesis hydrogen bonds 

分 类 号：O614.711[理学—无机化学]