超临界流体在非均相催化反应中的应用  

Application of Supercritical Fluids in Heterogeneous Catalytic Reactions

作　　者：李雪[1] 白雪峰[2] 刘宁生[2] 

机构地区：[1]辽宁石油化工大学环境工程系,辽宁抚顺113001 [2]黑龙江省石油化学研究院,黑龙江哈尔滨150040

出　　处：《化学与粘合》2003年第2期81-85,共5页Chemistry and Adhesion

基　　金：黑龙江省科学院重点基金项目

摘　　要：介绍了超临界流体的概念和超临界流体独特的性质。从化学动力学和热力学的角度,阐述了超临界反应对化学反应的影响。重点对超临界反应在烷基化、异构化、氧化、加氢及F-T合成等非均相催化方面的应用进行综述。The supercritical fluids and the supercritical reactions were introduced in this paper. The influence of SCF on the chemical reactions was introduced in term of chemical kinetics and thermodynamics. Heterogeneous catalytic reactions in supercritical fluids such as alkylation, isomerization, oxidation, hydrogenation and Fischer-Tropsch synthesis were paid much attention in this review.

关 键 词：超临界流体 超临界反应 非均相催化 

分 类 号：O643[理学—物理化学]