合成乙二醇单烷基醚乙酸酯的催化剂研究(英文)  

Research on catalysis for synthesis of ethylene glycol monoether acetate

作　　者：文瑞明[1] 罗新湘[1] 丁亮中[1] 俞善信[1] 

机构地区：[1]湖南城市学院化学系,湖南益阳413049

出　　处：《湘潭师范学院学报（自然科学版）》2003年第1期84-86,共3页Journal of Xiangtan Normal University (Natural Science Edition)

基　　金：湖南省自然科学基金资助课题 ( 0 0JJY2 0 110 );湖南省教育厅科研基金资助课题 ( 0 1C0 2 2 )

摘　　要：详细介绍和评述了阳离子交换树脂、分子筛负载TiO2 /SO42 -、稀土盐、层柱状粘土等不同催化剂催化合成乙二醇单烷基醚乙酸酯的方法。探讨了用硫酸氢钠催化合成乙二醇单甲醚乙酸酯的最佳条件。结果表明 ,硫酸氢钠是催化合成乙二醇单甲醚乙酸酯的良好催化剂 ,用量少、收率高、操作简便。The catalytic synthesis of ethylene glycol monoether acetate using cation ion exchange resin, TiO2/SO42- to be carried by molecular sieves, rare-earth salt, pillared clay et al as catalysts are described in detail. The optimum reaction conditions of the synthesis of ethylene glycol monomethyl ether acetate catalyzed by sodium bisulfate was probed. The results have proved that sodium bisulfate is good catalyst for synthesis of ethylene glycol monomethyl ether acetate, and it little amount of use, high yield, convenient to operate.

关 键 词：乙二醇单烷基醚 催化剂 酯化反应 

分 类 号：O643.364[理学—物理化学] TQ426[理学—化学]