过氧化氢氧化法合成C.I.酸性紫17  

The Synthesis of C.I. Acid Violet 17 by Oxidation with Hydrogen Peroxide

作　　者：潘明初[1] 

机构地区：[1]温州大学应用技术学院,温州325027

出　　处：《染料与染色》2003年第1期12-13,共2页Dyestuffs and Coloration

摘　　要：在催化剂存在下,以N-乙基-N-苄基苯胺磺化物与对-(N,N-二乙基)氨基苯甲醛在酸性条件下 于95℃～100℃进行缩合,在pH=5～6时,用30％过氧化氢氧化,合成了C.I.酸性紫17,氧化收率86.5％,成品中 铬含量为10.8mg/kg。C.I. Acid Violet 17 was synthesized by the condensation of sulfonatedN-ethyl-N-benzylaniline with p-(N,N-diethyl)aminobenzaldehyde in the presence of a catalyst and under acid condition at 95-100℃, then oxidation with 30% hydrogen peroxide at pH=5-6. The yield of the oxidation reaction was 86.5%; the chrome content of the product was 10.8mg/Kg.

关 键 词：过氧化氢 氧化法 合成 C.I.酸性紫17 N-乙基-N-苄基苯胺磺化物 对-(N N-二乙基)氨基苯甲醛 酸性染料 

分 类 号：TQ615.1[化学工程—精细化工]