树脂吸附处理模拟双酚A生产中含酚废水的研究  

Study on Adsorption Treatment of Phenol and Bisphenol A Solution with Resin XDA-2

作　　者：肖吉敏[1] 王槐三[1] 刘玉鑫[1] 寇晓康 王林元[1] 

机构地区：[1]四川大学高分子科学与工程学院,四川成都610065 [2]西安蓝深吸附分离材料有限责任公司,陕西西安710032

出　　处：《四川大学学报（工程科学版）》2003年第2期64-67,共4页Journal of Sichuan University (Engineering Science Edition)

摘　　要：采用国产新型大孔吸附树脂XDA-2对含有双酚A、苯酚和丙酮的模拟水样进行动态吸附处理,研究了总酚浓度、温度、流量、pH和丙酮浓度等因素对树脂吸附性能的影响,同时比较丙酮、甲醇和稀碱溶液在室温和加热条件下的解吸效率。结果显示,在温度低于35℃、流量不高于8BV/h、pH≤7的条件下,树脂对总酚浓度≤2300mg/L的模拟水样中苯酚和双酚A的吸附去除率均≥99%,丙酮浓度≤8000mg/L时树脂的工作吸酚量达到48～73mg/ml。用2BV的丙酮在常温条件下的解吸效率接近于100%,用浓度5%的NaOH水溶液在60℃时的解吸效率达到91%。A simulated wastewater sample containing bisphenol A, phenol and acetone was treated with new adsorption resin XDA-2. The adsorption parameters ,such as the concentrations of phenol and acetone, temperature, pH, and current velocity were investigated . The elution efficiency of resin by acetone, methol or 5 % NaOH water solution at room temperature or higher temperature were also measured. The adsorption efficiency of phenols reaches 99% under the following conditions : total phenols concentration ≤2300?mg/L, temperature ≤35?℃, flow rate ≤8?BV/h and pH≤7. The dynamic adsorption capacities of the resin are 48 ～ 73?mg/L when the concentration of acetone in water is below 8000?mg/L. The elution efficiency is near 100 % with 2 BV of acetone at room temperature. The elution efficiency is 91?% with 5?% NaOH water solution at 60 ℃. 

关 键 词：大孔吸附树脂XDA—2 双酚A 含酚废水 模拟水样 废水处理 苯酚 吸附性能 

分 类 号：X783[环境科学与工程—环境工程]