Optical Rotatory Feature of (R or S)-1,1′-Binaphthalene-2,2′-diol (BINOL) in Various Solvents  

作　　者：陈传福 李钟 艾敏 陈永明 习复 

机构地区：[1]Centre for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China

出　　处：《Chinese Journal of Chemistry》2003年第2期204-207,共4页中国化学（英文版）

基　　金：ProjectsupportedbytheNationalNaturalScienceFoundationofChina (No .2 99740 3 4)

摘　　要：The changes of the specific rotation and sign of optically active BINOL have been studied in polar/non polar solvents and at the different pH values of solvent. It is considered that these changes are determined by the equilibrium studies between cisoid and transoid conformations of BINOL with the same configuration ( R or S ) which related to the change of the dihedral angle between two naphthalene ring planes of BINOL.The changes of the specific rotation and sign of optically active BINOL have been studied in polar/non polar solvents and at the different pH values of solvent. It is considered that these changes are determined by the equilibrium studies between cisoid and transoid conformations of BINOL with the same configuration ( R or S ) which related to the change of the dihedral angle between two naphthalene ring planes of BINOL.

关 键 词：binaphthalene  2 2′  diol solute  solvent interaction specific rotation cisoid and transoid conformation 

分 类 号：O625.34[理学—有机化学] O645.163[理学—化学]