锌(II)与bipyO_2三核配合物的合成和气敏性  

Synthesis and gas sensitive properties of trinuclear complex of bipyO_2 with Zn(II)

作　　者：傅铁祥[1] 曹军[1] 

机构地区：[1]长沙电力学院化学系,湖南长沙410077

出　　处：《化学研究与应用》2003年第2期224-226,共3页Chemical Research and Application

基　　金：湖南省自然科学基金资助项目(O1JJY3010)

摘　　要：A trinuclear complex was synthesized by reaction of 2,2′-bipyridine1,1′dioxide with ZnCl2 in DMF solution.The ditrminations of elemental analysis,IR,UV,molar conductivity and TGDTA indicated the composition of the complex with formula Cl2.The study of sensitive properties showed the complex has good sensitivity and selectivity to ammonia.The sensor manufactured by the complex could be used in ammonia leakalarm and in production to control NH3.A trinuclear complex was synthesized by reaction of 2,2′-bipyridine1,1′dioxide with ZnCl2 in DMF solution.The ditrminations of elemental analysis,IR,UV,molar conductivity and TGDTA indicated the composition of the complex with formula Cl2.The study of sensitive properties showed the complex has good sensitivity and selectivity to ammonia.The sensor manufactured by the complex could be used in ammonia leakalarm and in production to control NH3.

关 键 词：锌(Ⅱ) bipy02 三核配合物 合成 气敏性 2 2’-联吡啶-1 1'’'’-二氧化物 

分 类 号：O614.241[理学—无机化学]