铜基低水碳比型高温变换催化剂制备工艺条件的研究  

STUDY ON THE TECHNOLOGY OF COPPER BASED CATALYST FOR HIGH TEMPERATURE SHIFT REACTION AT LOW WATER-CARBON RATIO

作　　者：李廷真[1] 王东升[1] 高俊[1] 牟占军[1] 金恒芳[1] 刘全生[1] 

机构地区：[1]内蒙古工业大学化工学院,内蒙古呼和浩特010062

出　　处：《内蒙古工业大学学报（自然科学版）》2002年第3期170-173,共4页Journal of Inner Mongolia University of Technology：Natural Science Edition

基　　金：国家自然科学基金(No.20066002);内蒙古教育厅基金(ZL9904)资助项目

摘　　要：以铜盐、锰盐为原料,详细研究了铜基低水碳比型CO高温变换催化剂的配方及制备工艺条件.在大量探索性试验的基础上,采用正交试验法对催化剂中的铜锰比、制备过程中铜盐、锰盐混合液浓度、中和温度、pH值以及焙烧温度等因素进行了系统的研究.结果表明,该催化剂的最佳制备条件为:铜锰比1/2,混合液浓度0.09～0.15g/ml,中和过程的温度30～55℃,pH值10～11,焙烧温度500～600℃.依照上述条件所制得的催化剂按高变催化剂的国标进行检测,其初活性(按CO转化率计)可达93%以上.The paper studies on the prescription and preparationcondition of the copper based shift reaction catalyst detailedly from nantokite and mangante as the resource.On the basis of exploratory research,the paper studies the technology of the catalyst,such as the ratio of Cu to Mn,the concentration of nantokite and mangante,neutralization temperature,pH and calcinations temperature systematically with the method of orthogonal design.The result indicates that the ratio of Cu to Mn:1/2,the concentration of nantokite and mangante:0.09~0.15 g/ml,neutralization temperature:30~55 ℃,pH:10~11 and calcinations temperature:500~600 ℃ are the best preparation conditions.The activity of the catalyst is above 93% by the standard of nation.

关 键 词：铜基 水碳比 高温变换 

分 类 号：TQ426.6[化学工程]