反饱和特性化合物锌-四苯并卟吩-巴豆酸-苯氧树脂的光吸收谱测定  

Optical Absorption Characteristics of an Organic Material Zntbp-CA-PhR

作　　者：李潞瑛[1] 赵有源[1] 于世瑞[1] 郑锐之[1] 

机构地区：[1]复旦大学光科学与工程系先进光子学材料与器件国家重点实验室,上海200433

出　　处：《光学学报》2003年第4期441-445,共5页Acta Optica Sinica

基　　金：国家自然科学基金 ( 6 98880 0 1;198340 30 )资助课题。

摘　　要：报道一种新型的有机材料锌四苯并卟吩巴豆酸苯氧树脂 (缩写为Zntbp CA PhR)体系薄膜样品的吸收谱的测定 ,及其主要吸收谱带在激光作用下的变化情况及动力学过程。实验观察到此种材料显著的饱和及反饱和吸收现象 ,并观察到它的再反饱和过程 ,定性分析了变化过程中的物理机制。这种特征在可见光波段一个较宽的区域内都会出现。所获结果为此种有机材料在光谱域信息存储和光学限制等方面的应用提供了理论和实验依据。The measurement of optical absorption spectrum of a novel organic material Zn-tetrabenzoporphin-crotonic acid-phenoxy resin (Zntbp-CA-PhR) is reported. The nonlinear absorptive characteristic of the sample illuminated by lasers was studied. And the absorption alternation and kinetic process of the major spectrum bands were observed. The saturable absorption (SA) and reverse saturable absorption (RSA) appeared as the input fluence increases and re-reverse resaturable absorption process of the material was demonstrated in the experiment. These properties occur in a broad range of visible spectrum. The physical mechanism during the whole course is qualitatively analysed. The present work offers an evidence both in theory and experiment for organic material applying in frequency domain optical information storage and optical limiting.

关 键 词：饱和吸收 反饱和吸收 锌四苯并卟吩—巴豆酸—苯氧树脂 光学信息存储 吸收谱 有机材料 

分 类 号：O621.22[理学—有机化学] TQ594[理学—化学]