DMC催化剂催化环氧丙烷聚合反应的研究  

Study on Polymerization of Propylene Oxide with DMC Catalyst

作　　者：李俊贤[1] 周集义[1] 王文浩[1] 王建伟[1] 李新豪[1] 贾利亚[1] 

机构地区：[1]黎明化工研究院,洛阳471001

出　　处：《化学推进剂与高分子材料》2003年第2期1-3,共3页Chemical Propellants & Polymeric Materials

摘　　要：研究了使用DMC催化剂制备环氧丙烷聚醚时 ,聚合温度、催化剂浓度、加料速度对聚醚相对分子质量和相对分子质量分布的影响规律。采用连续加起始剂的操作方式可窄化聚醚的相对分子质量分布 。The effects of temperature,concentration of catalyst and feeding rates of monomer on molecular weight and molecular weight distribution in polymerization of propylene oxide with DMC catalyst were discussed.Adding starter continuously can make molecular weight distribution narrow.Adjusting acid number of starter can reduce polymerization induction time.

关 键 词：DMC催化剂 催化 环氧丙烷 聚合反应 研究 聚醚 

分 类 号：TQ316.334[化学工程—高聚物工业]