Synthesis,X—Ray Structure and Characterization of a Triruthenium Cluster Complex Ru^Ⅲ3(μ3—O)(μ—CH3COO)6(py)2Cl with Four Steps One—electron Redox Processes  

Synthesis,X-Ray Structure and Characterization of a Triruthenium Cluster Complex Ru_3~Ⅲ(μ_3-O)(μ-CH_3COO)_6(py)_2Cl with Four Steps One-electron Redox Processes

作　　者：Jing Lin CHEN Gang Qiang YIN Zhong Ning CHEN 

机构地区：[1]State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Fuzhou 350002

出　　处：《Chinese Chemical Letters》2003年第5期519-522,共4页中国化学快报(英文版)

基　　金：This work was financially supported by the National Natural Science Foundations of China(No.20171044 and 20273074);Chinese Academy of Sciences for"hundred talents".

摘　　要：The synthesis and crystal structure of oxo-centered carboxylate-bridge trinuclear ruthenium complex, Ru3O(CH3COO)6(py)2Cl (py = pyridine) (1), are reported herein. The complex 1 has been characterized by IR, cyclic voltammetry (CV), UV-Vis and X-ray crystal analysis. The complex 1 in 0.1 mol/L (n-C4H9)4NPF6-CH2Cl2 solution at room temperature shows four one- electron redox processes at E1/2 = -1.38, -1.20, -0.17 and 1.07 V vs. Ag/AgCl.The synthesis and crystal structure of oxo-centered carboxylate-bridge trinuclear ruthenium complex, Ru3O(CH3COO)6(py)2Cl (py = pyridine) (1), are reported herein. The complex 1 has been characterized by IR, cyclic voltammetry (CV), UV-Vis and X-ray crystal analysis. The complex 1 in 0.1 mol/L (n-C4H9)4NPF6-CH2Cl2 solution at room temperature shows four one- electron redox processes at E1/2 = -1.38, -1.20, -0.17 and 1.07 V vs. Ag/AgCl.

关 键 词：Crystal structure RUTHENIUM CARBOXYLATE electrochemistry. 

分 类 号：O641.4[理学—物理化学]