双金属层状配位聚合物{[ML][Fe^IIFe^III(ox)_3]·H_2O}_∞的合成和波谱表征  

Syntheses and Spectra Characterization of Bimetallic Coordination Polymers with Layer Structure{[ML][Fe^IIFe^III(ox)_3]·H_2O}_∞

作　　者：刘光祥[1] 陈友存[1] 周宏[1] 任小明[1] 

机构地区：[1]安庆师范学院化学系,安庆246011

出　　处：《Chinese Journal of Chemical Physics》2003年第2期141-145,共5页化学物理学报（英文）

基　　金：国家自然科学基金 (2 0 1710 0 1);安徽省科技厅"十五"攻关项目 (0 10 12 0 38);安徽省教育厅基金 (2 0 0 1kj16 2 )资助

摘　　要：合成和表征了两种新的Schiff碱配合物 [ZnL(ClO4)·4H2 O (A)和CdL(ClO4)·3H2 O (B) ],其中L =2 { [2 (Aminomethyl amino) ethylimino] methyl} phenol.A(或B)、FeSO4·7H2 O和K3 [Fe(ox) 3 ]·3H2 O进一步反应 ,生成了配位聚合物 { [ML][FeIIFeIII(ox) 3 ]·H2 O} ∞ ,其中M =Zn2 + (C)或Cd2 + (D) .红外光谱和M ssbauer谱测定结果表明 ,C和D具有二维层状结构 ,其阴离子层由 [FeIIFeIII(ox) 3 ]-单元构成 .Two new Schiff base complexes, ZnL(ClO 4)·4H 2O (A) and CdL(ClO 4)·3H 2O (B), where L=2 {\[2 (Aminomethyl amino) ethylimino\] methyl} phenol, have been synthesized and characterized by elemental analysis and infrared spectra. Further, two new bimetallic coordination polymers, {\\[Fe II Fe III (ox) 3·H 2O\]} ∞ were synthesized and characterized, in which ox 2- =oxalate, M=Zn 2+ (C) or Cd 2+ (D). The bonds of ν as (C=O), δ(C=O) were at 1635, 818 cm -1 for complex C and 1646, 820 cm -1 for complex D, respectively. The results of Mssbauer spectra of C and D revealed that there exist two kinds of valence ions. The two bimetallic coordination polymers feature the 2 D layer structure in the solid state, and their anions layer was formed by the \[Fe II Fe III (ox) 3\] - unit.

关 键 词：双金属层状配位聚合物 合成 表征 草酸根桥联 铁 

分 类 号：O641.4[理学—物理化学]