反-1,4-丁二烯-α-烯烃共聚物  

Copolymers of trans -1,4-butadiene -α-olefin

作　　者：贺爱华[1] 王日国[2] 黄宝琛[2] 焦书科[3] 

机构地区：[1]中国科学院化学研究所分子科学中心工程塑料国家重点实验室,北京100080 [2]青岛科技大学高分子材料科学与工程学院,山东青岛266042 [3]北京化工大学材料科学与工程学院,北京100029

出　　处：《合成橡胶工业》2003年第3期189-192,共4页China Synthetic Rubber Industry

摘　　要：综述了国内外合成反-1,4-丁二烯-α-烯烃共聚物的各种催化体系,以及共聚物的结构、组成及物理机械性能,并对各种催化体系进行了评价。丁二烯与乙烯共聚合,主要得到结晶型聚合物;二烯烃的加入明显降低了催化体系的催化活性;钒系催化剂合成的丁二烯与丙烯共聚物为交替共聚物,钛系所合成的共聚物交替度与规整度不高;丁二烯与其他高碳数α-烯烃共聚合,所得的共聚物相对分子质量很低。The trans-1,4-butadiene -α-olefin copolymers with different catalyst systems were re-viewed with 23references.The structures and me-chanical properties of trans-1,4-butadiene -olefin copolymers were also introdu ced.Copolymer-ization of butadiene and ethylene ma inly produced crystalline copolymers,the cataly tic efficiency de-creased greatly with the addition of di-olefin.Copolymers of butadiene and propylene syn-thesized with vanadium catalysts we re alternativecopolymers,while copolymers synth esized with tita-nium catalysts had lower alternativ e degree and reg-ularity compared to vanadium cataly sts.Copolymer-ization of butadiene and other highα-olefin gen-erally produced copolymers with rather low relative molecular mass.

关 键 词：反-1 4-丁二烯-α-烯烃共聚物 微观结构 物理机械性能 综述 

分 类 号：TQ325[化学工程—合成树脂塑料工业]