苯胺及吡咯的共聚合研究进展  

PROGRESS IN THE COPOLYMERIZATION INVESTIGATION OF ANILINE AND PYRROLE

作　　者：陈润峰[1] 李新贵[1] 赵红[1] 

机构地区：[1]同济大学材料学院,混凝土国家重点实验室,高分子材料系,上海200092

出　　处：《高分子材料科学与工程》2003年第3期6-11,共6页Polymer Materials Science & Engineering

基　　金：国家自然科学基金 (2 0 1 74 0 2 8);复旦大学聚合物分子工程教育部重点实验室资助项目

摘　　要：综述了苯胺及吡咯的共聚合机理、共聚物结构和共聚研究现状。着重讨论了取代基对聚合过程和聚合物性能的影响 。Copolymerization is one of the most effective methods to improve the physical and mechanical properties of polyaniline and polypyrrole and has been investigated extensively. In this paper, the copolymerization mechanism, the structure of the copolymers, and the state of the current study of them were reviewed. Copolymerizing with substituted derivatives, with other conjugated monomers, and with non conjugated monomers are three major research directions in this field and were discussed in corresponding three parts. In the first part, it was concentrated on the influence of the substitutes on the polymerization process, and on the structure and properties of the copolymers. In the latter two parts, the copolymerization technology was stressed.

关 键 词：苯胺 吡咯 共聚合 研究进展 取代基 共轭单体 非共轭单体 导电高分子 

分 类 号：TQ323.9[化学工程—合成树脂塑料工业] TQ324.8