双(6,7-二甲硫基四硫富瓦烯-2,3-二硫)金属配合物的合成及其电化学性质  

Synthesis of Bis(6,7-Bismethylthio Tetrathiafulvalene-2,3-Dithio) Metal Complexes And Its Electrochemistry Properties

作　　者：常文贵[1] 

机构地区：[1]皖西学院化学系,安徽六安237012

出　　处：《皖西学院学报》2003年第2期36-38,共3页Journal of West Anhui University

摘　　要：以 6 ,7-二甲硫基四硫富瓦烯 - 2 ,3-二硫醇盐为配体合成了两种新的双 (6 ,7-二甲硫基四硫富瓦烯 - 2 ,3-二硫 )金属配合物 ,利用循环伏安法研究了它们的电化学性质 ,并讨论了其紫外 -可见光谱和形成中性产物的原因。That the ligand of 6,7-bismethylthio tetrathiafulvalene-2,3-dithiolate salt was treated with metal(II) cation yielded two new bis(6,7-bismethylthio tetrathiafulvalene-2,3-dithio)metal complexes in this paper.This is a new method of synthesizing bridged tetrathiafulvalene derivativs.The electrochemistry properties of the complexes determined by the cyclic voltammetry were discussed,UV-VIS and the reason of giving neutral complexes were reported,too.

关 键 词：双(6 7-二甲硫基四硫富瓦烯-2 3-二硫)金属配合物 电化学性质 合成 循环伏安 紫外-可见光谱 

分 类 号：O635.1[理学—高分子化学] O646.5[理学—化学]