Dioxygen Affinities and Catalytic Oxidation Performance of Cobalt (Ⅱ)Complexes with N—Aryl Hydroxamic Acid  

Dioxygen Affinities and Catalytic Oxidation Performance of Cobalt (II)Complexes with N-Aryl Hydroxamic Acid

作　　者：Chun Chun ZHANG Wei ZENG Jian Zhang LI Sheng Ying QIN 

机构地区：[1]Department of Chemistry,Sichuan University,Chengdu 610064

出　　处：《Chinese Chemical Letters》2003年第6期627-630,共4页中国化学快报(英文版)

基　　金：This work is supported by the National Natural Science Foundation of China(Grant No.2007205).

摘　　要：The oxygenation of cobalt (II) hydroxamates (CoL2) and its catalytic performance in oxidation of p-xylene to p-toluic acid (PTA) were examined. The effects of X and Y bonded to hydroxamate group on dioxygen affinities and catalytic oxidation performance were also investigated.The oxygenation of cobalt (II) hydroxamates (CoL2) and its catalytic performance in oxidation of p-xylene to p-toluic acid (PTA) were examined. The effects of X and Y bonded to hydroxamate group on dioxygen affinities and catalytic oxidation performance were also investigated.

关 键 词：Cobalt (II) hydroxamates dioxygen affinities catalytic oxidation p-xylene. 

分 类 号：O643.3[理学—物理化学]