几种二胺合钴(Ⅲ)类配合物的合成及核磁共振结构测定  

Synthesis of some Kinds of Cobalt(Ⅲ) Coordination Complex and their Nuclear Magnetic Resonance Spectroscopy

作　　者：燕萍[1] 徐大军[1] 

机构地区：[1]沈阳化工学院应用化学系,辽宁沈阳110142

出　　处：《沈阳化工学院学报》2003年第2期85-88,共4页Journal of Shenyang Institute of Chemical Technolgy

摘　　要：　合成4种含氨、乙二胺、丙二胺、环己二胺等配体的钴(Ⅲ)配合物,与文献方法相比,其合成过程更为简单.合成产物经提纯后,用1H、13C、59Co核磁共振及红外光谱等现代物理方法对其结构进行了测定.In this paper, Cobalt(Ⅲ) coordination complex containing ammonia, ethylene diamine, 1,2propylene diamine, 1,2cyclohexanediamine ligand have been synthesized.The present method is more simple than the literature method. After purification,structure of these coordination complex were characterized by \{\}\+1H?\{\}\+\{13\}C?\{\}\+\{59\}Co nuclear magnetic resonance spectroscopy and infrared spectroscopy.

关 键 词：^59Co-NMR谱 配合物 合成 

分 类 号：O614.812[理学—无机化学]