N,N-二甲基苯甲醛连氮及其Cu(I)配合物的合成与表征  

Synthesis and characterization of N,N-dimethylbenzalazine and its Cu(I) complex

作　　者：裘灵光[1] 田玉鹏[1] 

机构地区：[1]安徽大学化学化工学院,安徽合肥230039

出　　处：《安徽大学学报（自然科学版）》2003年第2期80-84,共5页Journal of Anhui University(Natural Science Edition)

基　　金：国家自然科学基金资助项目(29871001)

摘　　要：设计合成了一种新的连氮类D-π-D型化合物N,N-二甲基苯甲醛连氮(L1),制备了其双核Cu(I)的配合物,分别用元素分析、红外光谱、核磁共振、电子自旋共振波谱、质谱及电喷雾质谱等进行了表征,并对它们的荧光性质进行了初步研究。In this paper,a new azine compound,N-dimethylbenzalazine and its Cu(I) complex were designed and synthesized,and characterized by element analysis,IR,1HNMR,ESR,MS and FAB-MS. Structure and fluorescent spectra of ligand L1 and complex Cu2L13(ClO4)2 were studied. The result shows that the kind of the ligand and its copper (I) complex are likely to exhibit third-order nonlinear optical activity.

关 键 词：N N-二甲基苯甲醛连氮 铜配合物 合成 结构表征 连氮类化合物 D-π-D型化合物 

分 类 号：O614.121[理学—无机化学]