三维无机-有机杂化骨架微孔化合物[Co_3(BDC)_3(EG)_4]·2DMF的合成与结构  

Synthesis and Characteristic of 3-D Inorganic-organic Hybrid Framework Microporous Material [Co_3(BDC)_3(EG)_4]·2DMF

作　　者：方千荣[1] 石鑫[1] 辛明红[1] 吴刚[1] 田歌[1] 朱广山[1] 李亚丰[1] 叶玲[1] 王春雷[1] 张震东[1] 唐璐璐[1] 裘式纶[1] 

机构地区：[1]吉林大学化学学院,无机合成与制备化学国家重点实验室,长春130023

出　　处：《高等学校化学学报》2003年第6期980-982,共3页Chemical Journal of Chinese Universities

基　　金：国家重大基础研究计划"九七三"项目 (批准号 :G2 0 0 0 0 775 0 7);国家自然科学基金 (批准号 :2 98730 17和 2 0 10 10 0 4)资助

摘　　要：A 3-D inorganic-organic hybrid framework microporous material [Co 3(BDC) 3(EG) 4]·2DMF was synthesized under mild conditions and its crystal structure was determined by using single crystal X-ray diffraction. The crystal structure was solved by a direct method and refined by full-matrix least-square method. The crystal is the triclinic system and belongs to space group P-1 with a=9.978(2) nm, b=11.223(2) nm, c=11.283(2) nm, α=102.26(3)°, β=113.52(3)°, γ=92.73(3)°, V=6.329(2) nm 3, Z=1, D c=1.565 Mg/m 3, M r=1 063.59, μ=1.183 mm -1, F(000)=541, GOF=1.024, R=0.044 2, wR=0.124 9.A 3-D inorganic-organic hybrid framework microporous material [Co 3(BDC) 3(EG) 4]·2DMF was synthesized under mild conditions and its crystal structure was determined by using single crystal X-ray diffraction. The crystal structure was solved by a direct method and refined by full-matrix least-square method. The crystal is the triclinic system and belongs to space group P-1 with a=9.978(2) nm, b=11.223(2) nm, c=11.283(2) nm, α=102.26(3)°, β=113.52(3)°, γ=92.73(3)°, V=6.329(2) nm 3, Z=1, D c=1.565 Mg/m 3, M r=1 063.59, μ=1.183 mm -1, F(000)=541, GOF=1.024, R=0.044 2, wR=0.124 9.

关 键 词：三维无机-有机杂化骨架微孔化合物 [CO3(BDC)3(EG)4]·2DMF 合成 结构 微于L材料 钴酸盐 

分 类 号：O614.812[理学—无机化学] TB383[理学—化学]