含氯聚硅烷的合成与表征  

Studies on the Synthesis and Characterization of Polysilanes Containing Chlorine

作　　者：曾红梅[1] 苏志珊[1] 马洪[1] 傅鹤鉴[1] 陈德本[1] 

机构地区：[1]四川大学化学学院,成都610064

出　　处：《四川大学学报（自然科学版）》2003年第3期542-545,共4页Journal of Sichuan University(Natural Science Edition)

基　　金：国家自然科学基金(59873015;29771024)

摘　　要：将光敏基团Cl直接键连在聚硅烷大分子上,用3种方法合成了含氯聚硅烷:①用硅氢化反应将氯丙烯加成到聚硅烷上;②用含苯基聚硅烷中的苯环进行氯甲基化反应;③在Wurtz缩合反应完成后直接从反应体系中将端基含氯的聚硅烷分离出来.对产物分别进行了1HNMR、FT IR、GPC和XPS表征.The photosensitivity radicalCl was directly bonded with polysilane molecules. The polysilanes containing chlorine were synthesized by three ways: ①Through hydrosilylation reaction the propylene chloride was added to polysilanes containing Si-H. ②The containing chlorine polysilanes were synthesized by chloromethylation reaction of polysilanes with Ph. ③After complete of Wurtztype reductive condensation, the polysilanes with endCl directly were separated from reaction system. The polysilanes containing chlorine were characterized and analyzed by the 1HNMR, FTIR, GPC and XPS.

关 键 词：含氯聚硅烷 硅氢化反应 氯甲基化反应 

分 类 号：O627.41[理学—有机化学]