四(对-硝基)苯基卟啉配合物的合成和光谱性质  

Studies on Preparation and Spectroscopic Properties of Tetra-(p-nitrophenyl)Porphyrinatometal Complexes

作　　者：师同顺[1] 郑国栋[1] 付振生[1] 曹锡章 王翠英[2] 

机构地区：[1]吉林大学化学系 [2]沈阳建筑工程学院

出　　处：《吉林大学自然科学学报》1992年第3期99-104,共6页Acta Scientiarum Naturalium Universitatis Jilinensis

摘　　要：用改进的Aider方法合成了四(对-硝基)苯基卟啉Cr(Ⅲ),Mn(Ⅲ),Fe(Ⅲ),Co(Ⅱ),Ni(Ⅱ),Cu(Ⅱ),Zn(Ⅱ)配合物。用元素分析、紫外可见光谱、红外光谱、激光拉曼光谱、X射线光电子能谱等方法表征了配合物的组成和结构。用紫外可见光谱和红外差谱研究了一氧化氮配合物的光谱性质。The improved Adler's method was used to prepare the complexes of tetra-(p-nitro-phenyl) porphyrinatometal. The structures and compositions of the complexes were determined by elemental ananlysis, UV, IR, Raman and XPS. Adducts of the complexes with nitric oxide were studied by UV-VIS spectra and infrared subtracted spectra.

关 键 词：卟啉 配合物 合成 一氧化氮 光谱 

分 类 号：O626.13[理学—有机化学]