二维无机-有机杂化层网骨架晶体的合成与结构  

Synthesis and Characteristics of 2-D Inorganic-Organic Hybrid Layered Net Framework Crystals

作　　者：石鑫[1] 方千荣[1] 吴刚[1] 田歌[1] 朱广山[1] 叶玲[1] 王春雷[1] 张震东[1] 裘式纶[1] 

机构地区：[1]吉林大学化学学院无机合成与制备化学国家重点实验室,长春130023

出　　处：《化学学报》2003年第6期863-868,共6页Acta Chimica Sinica

摘　　要：在温和条件下合成了二维层网结构的无机 -有机杂化晶体Zn(BDC) (C3 H3 N2 )·(DMF) (1)和Co2 (BDC) 2 (C5H5N) 4 ·2 (DMF)·(C5H5N) (2 ) ,并通过ICP和X射线单晶衍射分析等手段对其结构进行了表征 .1的晶胞数据 :C14 H14 N3 O5Zn ,Mr=3 69 65 ,单斜晶系 ,C2 /c空间群 ,晶胞参数a =2 10 5 9(4 )nm ,b =1 0 3 16(2 )nm ,c =1 483 6(3 )nm ,β =99 0 9(3 )° ,V =3 182 6(11)nm3 ,Z =4,DX=1 5 43Mg/m3 ,μ =1 5 71mm-1,F(0 0 0 ) =15 12 .最后的一致性因子为R =0 0 697,Rw=0 2 0 18.2的晶胞数据 :C47H47N7O10 Co2 ,Mr=987 78,单斜晶系 ,P2 (1) /n空间群 ,晶胞参数a =1 0 82 9(2 )nm ,b =1 5 43 1(3 )nm ,c =1 44 2 8(3 )nm ,β =10 1 65 (3 )° ,V =2 3 612 (8)nm3 ,Z =2 ,DX=1 3 91Mg/m3 ,μ =0 767mm-1,F(0 0 0 ) =10 2 4.最后的一致性因子为R =0 0 65 2 ,Rw=0 1888.1和 2的结构都是由无机簇M2 (CO2 ) 4 (M =Zn ,Co)通过苯环连接而形成的层网结构 .它们都存在由 4个无机簇与 4个苯环形成的环 ,其大小约为 0 .9nm× 0 9nm .由于咪唑和吡啶分别与 1和 2无机簇的两极配位 。Two 2-D inorganic-organic hybrid layered network materials Zn(BDC) (C3H3N2) . (DMF) (1) and Co-2-(BDC)(2)(C5H5N)(4).2(DMF)(C5H5N)(2) were synthesized under mild synthesis condition. Their crystal structures were determined. by using single crystal X-ray diffraction. Crystal structures were solved by direct method and refined by full-matrix least-square method. Compound 1 is monoclinic, space group C2/c with a = 2.1059(4) nm, b = 1.0316(2) nm, c = 1.4836(3) nm, beta = 99.09(3)degrees, V = 3.1826(11) nm(3), Z = 4, D-X = 1.543 Mg/m(3), C14H14N3O5Zn, M-r = 369.65, mu = 1.571 mm(-1), F (000) = 1512, R = 0.0697, R-w = 0.2018, and compound 2 is monoclinic, space group P2(1)/n with a = 1.0829 (2) nm, b = 1.5431 (3) nm, c = 1.4428 (3) nm, beta = 101.65 (3)degrees, V = 2.3612 (8) nm(3), Z = 2, D-X = 1.391 Mg/m(3), C47H47N7O10Co2, M-r = 987.78, mu = 0.767 mm(-1), F(000) = 1024, R = 0.0652, R-w = 0.1888. They are layered networks with 0.9 nm x 0.9 nm pore.

关 键 词：二维无机-有机杂化层网骨架晶体 晶体结构 层网结构 合成 分子筛 对苯二酸 

分 类 号：O72[理学—晶体学]