桥联聚倍半硅氧烷的近期研究进展——单体合成及应用  

Recent Research Progress of Bridged Polysilsesquioxanes——Monomer Synthesis and Applications

作　　者：刘丰祎[1] 符连社[1] 王俊[1] 张洪杰[1] 

机构地区：[1]中国科学院长春应用化学研究所稀土化学与物理重点实验室,长春130022

出　　处：《化学通报》2003年第6期382-387,403,共7页Chemistry

基　　金："973"稀土功能材料基础研究 (G19980 6130 7);国家自然科学基金( 2 99710 30 ;2 0 1710 4 3)资助项目

摘　　要：桥联聚倍半硅氧烷作为一种新型的有机 无机杂化材料在近十年的研究中引起了人们的极大关注 ,这种材料的单体可以通过不同的合成方法获得 ,为材料的设计和剪裁提供了极大的便利。本文综述了桥联聚倍半硅氧烷单体的合成方法 ,对其在光学、催化、吸附等方面的应用作了评述 ,同时将发光稀土配合物引入桥联聚倍半硅氧烷的研究作了介绍 。Bridged polysilsesquioxanes,a new class of organic\|inorganic hybrid materials,has drawn much attention of researchers in the field of materials during the last decade.The versatility of the synthesis of monomers offers the opportunity to design and tailor the materials with great flexibility. This review describes the synthesis of monomers of bridged polysilsesquioxanes and their applications in optics,catalysis,and adsorption.Also the incorporation of luminescent rare earth complexes in bridged polysilsesquioxanes is introduced in this review.The future trend of this field is also outlooked.

关 键 词：桥联聚倍半硅氧烷 单体合成 合成方法 有机-无机杂化材料 基团 

分 类 号：TB34[一般工业技术—材料科学与工程]