C_5、C_6正构烷烃异构化反应的热力学分析  

THERMODYNAMIC ANALYSIS ON n C_5, n C_6 PARAFFIN ISOMERIZATION

作　　者：刘铁生[1] 何奕工[1] 

机构地区：[1]中国石油化工股份有限公司石油化工科学研究院,北京100083

出　　处：《石油学报（石油加工）》2003年第3期94-98,共5页Acta Petrolei Sinica(Petroleum Processing Section)

基　　金：国家重点基础研究发展规划项目资助课题 (G2 0 0 0 0 480 0 2 )

摘　　要：对C5、C6正构烷烃异构化反应进行了详细的热力学分析。通过计算得到了不同反应温度下的异构化反应的平衡常数、产物分布和转化率。讨论了异构化反应的温度、压力和氢 /烃摩尔比对反应的平衡和产物分布的影响。Thermodynamic analysis on the n C 5, n C 6 paraffin isomerization reaction was worked out in detail. The thermodynamic equilibrium parameters,product distribution and conversion of isomerization at different temperatures were obtained by calculation. The effects of reaction temperature,pressure and H 2/paraffin mole ratio on reaction equilibrium and product distribution were also discussed.

关 键 词：C5 C6 正构烷烃 异构化反应 热力学 正戊烷 正已烷 

分 类 号：TQ221.1[化学工程—有机化工]