芳香醛与丙二酸亚异丙酯的固相缩合反应  

Solid Condensation Reactions of Isopropylidene Malonate with Aromatic Aldehydes

作　　者：王春[1] 张英群[1] 李敬慈[1] 李贵深[1] 李晓陆[1] 

机构地区：[1]河北农业大学理学院,保定071001

出　　处：《应用化学》2003年第8期809-813,共5页Chinese Journal of Applied Chemistry

基　　金：河北省自然科学基金资助项目 ( 2 9915 8)

摘　　要：The solid condensation of isopropylidene malonate with aromatic aldehydes were carried out by grinding at room temperature or heating at 110～120 ℃ to give 5 arylidene 2,2 dimethyl 1,3 dioxane 4,6 dione . Both conditions afford the condensation high reaction activity. The yield of the product under grinding for 20 min followed by standing for 48 h at room temperature is 56%～80% and that by heating at 110～120 ℃ for 12 min is 55%～74%, respectively.The solid condensation of isopropylidene malonate with aromatic aldehydes were carried out by grinding at room temperature or heating at 110～120 ℃ to give 5 arylidene 2,2 dimethyl 1,3 dioxane 4,6 dione . Both conditions afford the condensation high reaction activity. The yield of the product under grinding for 20 min followed by standing for 48 h at room temperature is 56%～80% and that by heating at 110～120 ℃ for 12 min is 55%～74%, respectively.

关 键 词：二甲基芳亚甲基二氧六环二酮 芳香醛 丙二酸亚异丙酯 固相缩合反应 

分 类 号：O621.3[理学—有机化学]