Coordination Triangular Prism of Bisilver Complex with Triply-bridged of Bis(diphenylphosphino)amine  

作　　者：施林熙 张礼仪 陈忠宁 

机构地区：[1]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China

出　　处：《Chinese Journal of Structural Chemistry》2003年第3期283-286,共4页结构化学（英文）

基　　金：This work was supported by NNSFC (No. 20171044) and the project for "undred Talents from" the Chinese Academy of Sciences

摘　　要：The binuclear complex [Ag2(m-Ph2PNHPPh2)3](ClO4)2CH2Cl2CH3OH (Ph2PNHP- Ph2 = bis(diphenylphosphino)amine) was prepared from the reaction of AgClO4 with bis- (diphenylphosphino)amine in equimolar ratio through self-assembly. The coordination cation affords a triply-bridging [Ag2L3]-type coordination moiety. The silver atom is in a trigonal planar environment with P3 coordination chromophore. The complex (C74H69Cl4N3O9P6Ag2) crystallizes in monoclinic, space group Cc with a = 18.3738(1), b = 20.0207(4), c = 20.5422(4) ? b = 95.829(1), V = 7517.5(2) 3, Z = 4, Mr = 1687.68, Dc = 1.491 g/cm3, F(000) = 3432, m = 0.848 mm-1, the final R = 0.0460 and wR = 0.0935 for 7005 observed reflections with I > 2s(I).

关 键 词：bis(diphenylphosphino)amine binuclear complex crystal structure SILVER 

分 类 号：O614.122[理学—无机化学] O641.4[理学—化学]