Dienone-phenol Rearrangement of C-9 Oxygenated Decalinic Dienone and Analogs through B-Ring Cleavage  

作　　者：Jing Chun CHEN Gang ZHOU Wei Dong LI Yu Lin LI 

机构地区：[1]National Laboratory of Applied Organic Chemistry and Institute of Organic Chemistry,Lanzhou University,Lanzhou 730000

出　　处：《Chinese Chemical Letters》2003年第7期689-692,共4页中国化学快报(英文版)

基　　金：This work was financially supported by the National Natural Science Foundation of China(Grant No.20072012 and 20272021);the Foundation for University Key Teacher by the Ministry of Education of China.

摘　　要：Dehydrogenation of 9-hydroxy decalinic enones and analogs with DDQ resulted in a formal dienone-phenol type rearrangement via B-ring cleavage, while the corresponding dienone acetates underwent base-catalyzed formal dienone-phenol type rearrangement analogously.Dehydrogenation of 9-hydroxy decalinic enones and analogs with DDQ resulted in a formal dienone-phenol type rearrangement via B-ring cleavage, while the corresponding dienone acetates underwent base-catalyzed formal dienone-phenol type rearrangement analogously.

关 键 词：Dienone-phenol rearrangement decalinic dienone DEHYDROGENATION DDQ. 

分 类 号：O621.2[理学—有机化学]