可交联含氟聚醚醚酮的合成  

Synthesis of Crosslinkable Fluorinated Poly(ether ether ketone)

作　　者：刘佰军[1] 呼微[1] 马晓野[1] 饶先花[1] 李婷[1] 姜振华[1] 吴忠文[1] 

机构地区：[1]吉林大学化学学院,长春130023

出　　处：《高等学校化学学报》2003年第7期1329-1331,共3页Chemical Journal of Chinese Universities

基　　金：国家自然科学基金 (批准号 :5 0 2 0 30 0 4)资助

摘　　要：A novel crosslinkable fluorinated poly(ether ether ketone) with acetylenylbenzene end groups was prepared by solution condensation. The chemical structure of such polymer was confirmed by FTIR and 1H NMR. The crosslinking behavior and thermal stability were investigated by DSC and TGA respectively. The DSC thermogram for the first heating run shows a glass transition of 6F-PEEK at about 395 K and a exothermic peak correspongding to the self-crosslinking reaction of fluorinated poly(ether ether ketong) at about 700 K. For the second heating run, the exothermic peak disappered and the glass transition shifted to a higher temperature. The crosslinked polymer shown excelent thermal stability and solvent-resistence. The temperature for 5% weight loss was 774 K and the self-crosslinked polymer was no more disolved by polar solvents, which disolved in before crosslinking, such as DMF, DMAc and NMP. This kind of polymer may be a potential material used as electro-optical devices.A novel crosslinkable fluorinated poly(ether ether ketone) with acetylenylbenzene end groups was prepared by solution condensation. The chemical structure of such polymer was confirmed by FTIR and 1H NMR. The crosslinking behavior and thermal stability were investigated by DSC and TGA respectively. The DSC thermogram for the first heating run shows a glass transition of 6F-PEEK at about 395 K and a exothermic peak correspongding to the self-crosslinking reaction of fluorinated poly(ether ether ketong) at about 700 K. For the second heating run, the exothermic peak disappered and the glass transition shifted to a higher temperature. The crosslinked polymer shown excelent thermal stability and solvent-resistence. The temperature for 5% weight loss was 774 K and the self-crosslinked polymer was no more disolved by polar solvents, which disolved in before crosslinking, such as DMF, DMAc and NMP. This kind of polymer may be a potential material used as electro-optical devices.

关 键 词：可交联含氟聚醚醚酮 合成 工程塑料 苯乙炔端基 

分 类 号：TQ326.5[化学工程—合成树脂塑料工业]